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  • Scientists are looking into sustainably powering entire cities, and with liquid-based redox

  • flow batteries, we're one step closer to making that happen.

  • If we're ever going to replace fossil fuels with renewable sources like solar and wind

  • power, then we're going to need a way to store energy for when it's dark and not

  • windy, or just for when the demand for power exceeds the output.

  • If you're familiar with any sort of electronic device, then there is one pretty obvious answer:

  • batteries.

  • Charge them up when demand is low but output it high, then let the juice loose when that

  • flips.

  • But there are different battery types, and all have their own strengths and weaknesses.

  • This best battery for a job like this might be one that uses flowing liquids, called a

  • redox flow battery.

  • A redox flow battery is sort of a hybrid between a battery and a fuel cell.

  • It consists of two tanks of an electrolyte liquid, one positive and one negative.

  • In between the tanks is a cell stack, where the positive and negative solutions are pumped

  • to but kept separated by a membrane.

  • Inside the cell stack the ions in the negatively charged solution give up an electron, a process

  • called oxidation.

  • Those electrons are picked up by an electrode in the cell stack, and they travel through

  • whatever needs to be powered before arriving at another electrode on the other side of

  • the membrane.

  • There the ions in the positive solution pick up the electrons, a process called reduction.

  • This frees up positively charged hydrogen ions, which travel back across the membrane

  • and maintain the charge balance.

  • When charging up, the entire process happens in reverse.

  • But hold up, why go through all this when we have already lithium-ion batteries?

  • You know, the ones in cell phones, laptops, electric cars, and oh yeah, household battery

  • packs designed for exactly this purpose?

  • The problem is that while a big ol' lithium-ion battery might be suitable for your house,

  • they don't scale up well for something as big as an entire city.

  • Lithium isn't an abundant material either, so it's not sustainable to use it for these

  • huge applications.

  • And anyone who's had the same phone for more that a couple years can tell you that

  • lithium-ion batteries degrade and lose their ability to hold a charge over time.

  • On the other hand, flow cell batteries have qualities that make them perfect for large-scale

  • power storage, like scalability.

  • Need to store more energy?

  • Get bigger tanks that hold more solution, that's it.

  • Worried about degradation?

  • Some electrolyte solutions used in redox flow batteries can last for about 5,000 charge

  • cycles, five times longer than lithium-ion batteries.

  • What about price and sustainability?

  • Ah, about that

  • The most popular metal used in redox flow batteries is vanadium because it charges and

  • discharges reliably for thousands of cycles.

  • But the cost of vanadium is rising, and if vanadium redox batteries go mainstream that

  • price could skyrocket.

  • Researchers have tried to replace vanadium with organic molecules, but those tend to

  • degrade and need replacement every few months, or the solution they're in has to be very

  • acidic or basic, which can damage pumps or be hazardous in case of a leak.

  • But scientists are undeterred, and recently researchers from USC announced organic water-based

  • redox batteries that can last for about 15 years at one tenth the cost of a lithium-ion

  • battery.

  • So far the battery they've made is enough for the basic electricity demands of a single

  • house, but their goal is to one day have electricity on tap for entire mega-cities.

  • The technology is promising enough that China is building a massive vanadium redox flow

  • battery with a storage capacity of 800 Mega Watt hours.

  • That's enough for thousands of homes.

  • The battery is scheduled to come online by 2020.

  • China has plenty of vanadium reserves so they're not too concerned about it's cost, but if

  • organic flow cell batteries become comparable, those might not be too far behind.

  • One day in the near future, they might play a vital role in green energy grids around

  • the world.

  • If you liked this, subscribe!

  • And then maybe watch this cool video about how we can make batteries..out of DIAMONDS.

  • And fun fact: While Vanadium may not be the future of redox flow batteries, it is super

  • cool.

  • When vanadium gains electrons it changes color, going from yellow, to blue, to green, and

  • finally purple.

  • thanks for watching and we'll see you next time on Seeker.

Scientists are looking into sustainably powering entire cities, and with liquid-based redox

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