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  • - [Instructor] Let's talk a little bit

  • about metallic solids.

  • And here is an example of what

  • a metallic solid might look like.

  • They tend to be shiny like this.

  • Some would say lustrous.

  • Some of you might be guessing maybe this is some type

  • of aluminum or silver.

  • It actually turns out that this is sodium.

  • Our same friend sodium that we saw bonding with chlorine

  • to form sodium chloride and form ionic solids,

  • it can actually bond with itself with metallic bonds.

  • This right over here,

  • you might guess is silver or something.

  • It actually turns out this is calcium.

  • And I know what you're thinking.

  • Isn't calcium kind of this chalky white powder?

  • Well no, those are compounds formed with calcium,

  • things like calcium oxide.

  • But this right over here is pure calcium.

  • And the reason why it has to be in this container,

  • it is highly reactive with oxygen.

  • So that's not oxygen that is in this container.

  • It's some form of inert gas.

  • But calcium when it just bonds to itself

  • with metallic bonds, which we'll talk about in a little bit,

  • it also looks kind of similar.

  • It's this shiny, metallic, or lustrous look to it.

  • And what do you think this is?

  • Well this is something we're used to associating

  • with metals, this is gold.

  • But once again, you can see it has this lustrous property.

  • So what is it about metals or metallic solids

  • that allow them to be lustrous in this way

  • and have other properties that we're about to see?

  • And to understand that, we just have to look at

  • the periodic table of elements.

  • And that most of the periodic table of elements

  • is actually some form of metal.

  • You have in red right over here, this group one elements,

  • not including hydrogen.

  • Those are your alkali metals,

  • and you have your alkaline earth metals,

  • your transition metals,

  • your post-transition metals, your metalloids.

  • It's really only what you see in yellow and blue here

  • that are not your metals.

  • So how do metals form solids when you just have

  • a pure sample of them?

  • Well the general idea, you can look at your alkali metals,

  • they all have that one valence electron.

  • And to get to that stable outer shell,

  • it's much easier for them to give away a valence electron.

  • And that's why we often see these folks are dissipating

  • in ionic bonds.

  • They can be ionized quite easily.

  • But if you have a pure sample of them,

  • they can contribute electrons

  • to a sea of electron, one each.

  • These alkaline earth metals,

  • they have two valence electrons.

  • They too can be ionized or if you have a pure sample

  • like in a calcium, they can contribute two valence electrons

  • to a sea of electrons.

  • And the transition metals here have a similar ability

  • to contribute valence electrons.

  • And so in general, we can view metallic solids

  • as having cations, these positively charged cations

  • in a sea of electrons.

  • So you have all these electrons here.

  • I'll just draw all these minus charges that they're in.

  • Where do those electrons come from?

  • Well if you're looking at the alkali metals,

  • each of those atoms could give one electron to that sea

  • because it doesn't really want that valence electron.

  • If you're talking about alkaline earth metals,

  • they could each donate two electrons to that sea.

  • Now given that you have this positive charge

  • in this sea of electrons,

  • what are you think of the properties?

  • How good do you think this will be

  • at conducting electricity or heat?

  • And many of you might guessed, if you looked at a wire,

  • wires are made out of metals, because they are excellent

  • at conducting electricity, or they tend to be excellent

  • at conducting electricity, because you have

  • all of these electrons that can move around.

  • And so if you apply a voltage, they will start moving

  • and conduct electricity.

  • And those electrons can also be good at conducting

  • thermal energy or heat.

  • Now what would be, we already talked about them

  • having the shiny, lustrous property,

  • but how easy would it be to bend them?

  • Ionic solids, we talked about

  • they can be strong but brittle.

  • As soon as you try to shift them around a little bit,

  • they can break.

  • But what do you think is going to happen here?

  • If let's say right over here, I were to push really hard

  • and on the top I would have pushed really hard to the left.

  • Do you think this will be brittle?

  • Or do you think it will be malleable?

  • It's easy to bend.

  • Well if you have a pure metallic solid,

  • it's actually quite malleable.

  • If you just took this top part and pushed it

  • to the left like this, no big deal.

  • You have those cations that are still in those

  • that sea of electrons.

  • And that's generally true of metallic solids.

  • They're very malleable.

  • They are not brittle.

  • In fact, so much so that often times we want them

  • to be a little bit more rigid.

  • We want them to be a little bit harder.

  • And that's why we might do things like add other elements

  • into the metallic solid.

  • For example, pure iron is reasonably malleable.

  • But if you wanna make it stronger,

  • you could stick carbon atoms in between.

  • For example, you could put a carbon atom there,

  • or carbon atom over there.

  • And that way, it kind of disrupts

  • this electron sea a little bit.

  • So it's not quite as malleable.

  • It'll be stronger and more rigid.

  • So I'll leave you here.

  • This is just an extension of what we've already learned

  • about metals and metallic bonds.

  • To just realize why most of the periodic table of elements

  • that we're familiar with has some of these properties

  • when they are, when you have pure solids of them.

- [Instructor] Let's talk a little bit

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