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MAREN: So if you watched our previous episode on how batteries work,
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you'll know that batteries are complicated.
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They come in all shapes, sizes, charge capabilities,
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and we use them in everything.
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And if there's one battery technology that sets the gold standard,
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it's the lithium-ion battery.
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These batteries are one of the only types
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to pack powerful energy storage
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in a small and lightweight design.
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So, when designing battery technologies for the future,
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the challenge is to improve upon the advantages
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that the lithium-ion battery already has.
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Because even though lithium-ion batteries
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currently dominate the global battery market,
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there are quite a few things about them that could be improved,
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like power output, energy capacity,
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cost, lifespan, and safety.
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Now some of the most promising designs
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for giving lithium-ion battery technology a boost
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are the lithium-silicon battery,
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the lithium-sulfur battery,
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solid-state lithium-ion batteries
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and one that's a common nation of approaches.
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And changing out the materials used
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to make anodes, cathodes and electrolytes
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is exactly what scientists have been doing.
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But what is it gonna take for one of these
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to become the new battery of the future?
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It's important to note that a simple change
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in a battery's design can significantly affect
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its voltage and storage capacity.
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Here I've made a really simple homemade battery
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with 14 cells using an ice cube tray,
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steel screws, copper wire, a couple electrical leads,
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and this voltmeter.
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And the way this works is that each little ice cube tray
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is its own battery cell.
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So you've got the copper acting like the cathode.
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It's gaining electrons.
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The steel is acting as the anode.
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It's losing electrons.
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And the salt water is acting as my electrolyte,
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allowing that flow of charges.
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Now, when I hook it up to the voltmeter,
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you can see I am reading a voltage of around 200 millivolts.
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Now, what I'm interested in is what would happen
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if we changed out the electrolyte solution
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to the, say, vinegar.
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Lemon juice.
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So all these sorts of things can make a significant impact
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on the voltage and the storage capacity of the battery.
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MAREN: First up, silicon anode batteries.
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Remember that anodes are the negative electrode within a call?
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Well, like we talked about in the last episode,
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the current most popular anode material
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in lithium-ion cells is graphite.
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This is because graphite's structure helps keep
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those lithium ions efficiently stored in the anode.
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But there is a maximum amount of lithium-ions
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that can be stored in the anode,
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and that determines the cell's capacity.
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And as it turns out,
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silicon does a much better job than graphite
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at absorbing and holding lithium-ions.
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And this means batteries can be made smaller,
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more energy-efficient, and cheaper.
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But, of course, this does all come with a catch.
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Silicon anodes have a tendency to dramatically expand
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when encountering lithium during charging.
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And those anodes also then shrink
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when the battery discharges.
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And this repeated expansion and contraction
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shortens the lifespan of the battery,
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and ultimately, its usefulness.
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But researchers like those at Enovix,
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are aiming to fix this problem.
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We don't eliminate anode expansion and contraction,
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but we do control them.
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Propendent 3D cell architecture
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enables us to integrate
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a very thin stainless steel constraint
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into our battery design.
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This applies a uniform force around the battery
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to constrain the silicon expansion within the cell.
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during the charging cycles and during discharge.
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MAREN: While some researchers have set their sights on the anode,
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others are experimenting with the cathode
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with one innovation being lithium sulfur cells.
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Lithium on its own is a very volatile substance.
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It reacts to air, it reacts to water.
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So what the OXIS scientists have done
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is taken sulfur as a non-conductive, very cheap material.
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and used the sulfur to act as a fire retardant
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around lithium metal,
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so that if air or water impacts lithium metal,
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thermal runaway, fire, explosion, doesn't take place.
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Sulfur cathodes, like their silicon anode counterparts,
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can absorb more lithium ions
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than the typical cobalt-based cathodes.
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offering a reduced battery cost
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with increased energy density and improved safety
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compared to lithium-ion batteries.
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HUW: Because one of the key factors
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of lithium sulfur
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is that it is 50 to 60% lighter than lithium-ion.
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Now, if you take a bus with a very large battery,
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if you can replace that technology with lithium-sulfur
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and you reduce the weight and still
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extend the distance covered,
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then you have a major breakthrough
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in the renewable transportation systems.
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But lithium-sulfur cells are still not quite perfect
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because they face the challenge
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of lithium-polysulfide formation,
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or what's known as the polysulfide shuttle.
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The sulfur electrode also expands and contracts
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as it cycles, which results in a loss of battery efficiency
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and power and energy density.
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But what if the answer isn't in the anode or the cathode?
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What about the electrolyte?
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Well, that's where solid state batteries come in.
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Solid state electrolytes have been around for a while
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and have recently caught on
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as a contender for future batteries
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because of their promise of improved safety.
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But solid state polymers can better withstand extreme conditions.
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So when heated, they behave like liquids,
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but they can operate without the danger of bursting into flames.
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Some researchers believe that solid state batteries
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could even give electric vehicles
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over 500 miles of range.
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And if we really let our imaginations run wild,
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using solid state batteries in solar powered vehicles
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like the ones that compete in the World Solar Challenge
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could potentially lead to even longer ranges.
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Now, what's the downside to these solid state batteries?
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Well, unlike liquid electrolytes,
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they can't stay in contact
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with every bit of the electrodes all the time.
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And this makes it harder for the ions
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to move between electrodes
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and create that flow of electricity that we need.
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But what if we were able to combine
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a few of these innovations that we've already talked about?
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We could now make a transition
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from liquid electrolyte to solid state lithium sulfur.
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And I'm talking about removing the diesel trucks, diesel buses,
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the lead based fuel that our aircraft consume.
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These are the biggest pollutants that we've got on the planet,
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and solid state is certainly the phenomenon
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that will render those achievements more realistic.
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MAREN: So OXIS Energy is currently not in the solar car market,
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but is instead focusing on aerospace,
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marine vessels, and electric vehicles.
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They're close to achieving an energy density
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of 500 watt-hours per kilogram
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with their battery,
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and have already set a new target
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of 600 watt-hours per kilogram.
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Essentially, that means a battery like this in the future
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could be capable of powering an electric car
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for 1,000 kilometers on a single charge.
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By comparison, Tesla's Panasonic lithium-ion battery cells,
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which are currently the most commercially advanced,
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are about half as energy dense.
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So all of the battery innovations we've covered
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are definitely impressive.
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But if we want more solar vehicles on the roads,
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we're gonna need a powerful battery storage system
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with high energy density, high efficiency,
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and the ability to last long on the road, rain or shine,
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because currently, none of the options on the market
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or even in development totally do the job.
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That's why it's important to have events like the World Solar Challenge,
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'cause when creating a vehicle like this,
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you're pushing technology to its limit.